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The Fullerene Group in the Chemistry Department of Moscow State University certifies the fullerenes distributed by Term USA and conducts research on fullerenes and fullerene derivatives.

Contact for Research-Related Questions
Prof. Lev Sidorov
E-mail: sidorov@thermo.chem.msu.ru
Phone: +7(495)9391240, fax +7(495)9391240
Web: http://thermolab.chem.msu.ru
Mailing address:
Thermochemistry Lab
Department of Chemistry
Moscow State University
Leninskie Gory 1-3
119991, Moscow
Russia.

Principal Scientific Interests of the Fullerene Group

  • Preparation and characterization of inorganic fullerene derivatives (S.I. Troyanov, D.Sc.; A.A. Goryunkov, Ph.D.)
  • Ion-Molecular equilibria in the fullerene vapors (A. Y. Borshchevsky, Ph.D.; V.E. ALeshina, Ph.D.)
  • Combustion Calorimetry [formation enthalpy of C60, C70 and fluorofullerenes] (T.S. Papina, Ph.D.)
  • Adiabatic calorimetry (R.M. Varuschenko, D.Sc.) and DSC (N.V. Chelovskaya, Ph.D.)
  • Synthesis of modified phases of fullerite C60 (E.V. Skokan, Ph.D.)
  • Crystal structure of fullerene derivatives (S.I. Troyanov, D.Sc.)
  • HPLC Separation and purification of fullerenes and derivatives (A.A. Goryunkov, Ph.D.; N.B. Tamm, Ph.D.)

Publications 2008-2010

2008

S.M. Avdoshenko, I.N. Ioffe, A.A. Kozlov, V.Yu. Markov, E.N. Nikolaev, L.N. Sidorov. Novel possibilities in the study of isolated carbon nanotubes, Rapid Comm. in Mass Spectrom., 2008, 22, 1372-1376.

A.A. Goryunkov, E.S. Kornienko, T.V. Magdesieva, A.A. Kozlov, V.A. Vorobiev, S.M. Avdoshenko, I.N. Ioffe, O.M. Nikitin, V.Y. Markov, P.A. Khavrel, A.K. Vorobiev, L.N. Sidorov. Electrochemical, ESR and theoretical studies of [6,6]-opened C60(CF2), cis-2-C60(CF2)2 and their anions, Dalton Trans., 2008, 2981-2985.

R.V. Khatymov, V.Yu. Markov, R.F. Tuktarov, I.N. Ioffe, M.V. Muftakhov, S.M. Avdoshenko, A.V. Pogulay, L.N. Sidorov. Electron interaction with S6-C60(CF3)12: Energy pool of fullerene cage, Int. J. Mass. Spectrom., 2008, 272, 119-126.

T. Mutig, I.N. Ioffe, E. Kemnitz, S.I. Troyanov. Crystal and molecular structures of C2-C70(CF3)8·1.5 PhMe, Mendeleev Commun., 2008, 18, 73-75.

T. Mutig, E. Kemnitz, S.I. Troyanov. Synthesis and structural characterization of four isomers of C70(n-C3F7)8, Eur. J. Org. Chem., 2008, 3256-3259.

N.S. Ovchinnikova, D.V. Ignateva, N.B. Tamm, S.M. Avdoshenko, A.A. Goryunkov, I.N. Ioffe, V.Yu. Markov, S.I. Troyanov, L.N. Sidorov, M.A. Yurovskaya, E. Kemnitz. Regioselective synthesis and crystal structure of C70(CF3)10[C(CO2Et)2], New J. of Chem., 2008, 32, 89-93.

A.A. Popov, A.V. Burtsev, V.M. Senyavin, Dunsch, S.I. Troyanov. Spectroscopic and theoretical study of the dimeric fullerene complex (C70)2(Ti3Cl13)2, J. Phys. Chem., A, 2008.

N.B. Shustova, M.G. Serov, S.I. Troyanov. Molecular and crystal structure of the C60F18 adducts with bromine and carbon disulfide, Fullerenes, Nanotubes and carbon nanostructures, 2008, v. 16, 597-602.

S.I. Troyanov, E. Kemnitz. Mixed chlorotrifluoromethyl fullerene C60(CF3)12Cl12, Mendeleev Commun., 2008, 18, 27-28.

S.I. Troyanov, A.A. Goryunkov, N.B. Tamm, V.Yu. Markov, I.N. Ioffe, and L.N. Sidorov. Synthesis, structure and theoretical study of mixed fluoro-trifluoromethyl derivatives of C60. Molecular structures of C60F18(CF3)6 and C60F16(CF3)6, Dalton Trans., 2008, 2627-2632

Yuong-Jun Yu, Olga Solomeshch, Helena Chechik, A.A. Goryunkov, F.R. Tuktarov, Dong Hoon Choi, Jung-li Jin, Yoav Eichen, Nir Tessler. p-Type doping in organic light emitting diodes based on fluorinated C60, J. of Applied Physics, 2008, 104, 124505

2009

T. Mutig, S.M. Avdoshenko, E. Kemnitz, S.I. Troyanov. Synthesis and molecular structures of heptafluoroisopropylated fullerenes: C60(i-C3F7)8, C60(i-C3F7)6, and C60(CF3)2(i-C3F7)2, J. Fluorine Chem., 2009, v. 129, 630-633.

T. Mutig, E. Kemnitz, S.I. Troyanov. Trifluoromethyl derivatives of fullerene C70, C70(CF3)2, C70(CF3)8 and C70(CF3)14, Mendeleev Commun., 2009, 19, 30-31.

T. Mutig, E. Kemnitz, S.I Troyanov. "Trifluoromethyl derivatives of fullerene C70, C70(CF3)2, C70(CF3)8 and C70(CF3)14". Mendeleev Commun., 2009, 19, 30-31.

E. Kemnitz, S.I. Troyanov. "Connectivity Patterns of Two C90 Isomers Provided by the Structure Elucidation of C90Cl32", Angew. Chem. Int. Ed., 2009, 48, 2584.

N.B. Tamm, S.I. Troyanov. Isomer C78(2) captured as the perfluoroethyl derivative C78(C2F5)10, Mendeleev Commun., 2009, 19, 198-199.

N.B. Tamm, S.I. Troyanov. "Crystal and Molecular Structures of Trifluoromethyl Derivatives of Fullerene C86, C86(CF3)16 and C86(CF3)18", Crystallography Reports, 2009, 54, 598-602.

N.A. Samokhvalova, P.A. Khavrel, V.Yu. Markov, P.S. Samokhvalov, A.A. Goruynkov, E. Kemnitz, L.N. Sidorov, S.I. Troyanov. "Isolation and Structural Characterization of the Most Stable, Highly Symmetric Isomer of C60(CF3)18", Eur. J. Org. Chem., 2009, 2935-2938.

I.N. Ioffe, A.A. Goryunkov, N.B. Tamm, L.N. Sidorov, E. Kemnitz, S.I. Troyanov. "Fusing Pentagons in a Fullerene Cage by Chlorination: IPR D2-C76 Rearranges into non-IPR C76Cl24", Angew. Chem. Int. Ed., 2009, 48, 5904-5907.

N.B. Tamm, L.N. Sidorov, E. Kemnitz, S.I. Troyanov. "Isolation and structural X-ray investigation of perfluoroalkyl derivatives of six cage isomers of C84", Chem. Eur. Journ., 2009, 15, 10486-10492.

N.B. Tamm, I.N. Ioffe, E. Kemnitz, S.I. Troyanov. "Synthesis and molecular structure of pentafluoroethyl derivatives of C70: C70(C2F5)8 and C70(C2F5)10", Dalton Trans., 2009, 2740-2745.

N.B. Tamm, S.I. Troyanov. "Cage connectivities of C88(33) and C92(82) fullerenes captured as trifluoromethyl derivatives, C88(CF3)18 and C92(CF3)16", Chem. Commun., 2009, 6035-6037.

N.B. Tamm, L.N. Sidorov, E. Kemnitz, S.I. Troyanov. "Crystal Structures of C94(CF3)20 and C96(C2F5)12 Reveal the Cage Connectivities in C94(61) and C96(145) Fullerenes", Angew. Chem. Int. Ed., 2009, 48, 9102-9104.

S.I. Troyanov, N.B. Tamm, Ch. Chen, S. Yang, E. Kemnitz. "Synthesis and Structure of a Highly Chlorinated C78: C78(2)Cl30". Zeitschrift fur anorganische und allgemeine Chemie, 2009, 635, 1783-1786.

O.Yu. Solomeshch, J. Young, A.A Goryunkov, L.N. Sidorov, R.F. Tuktarov, D.H. Choi, H. Dong , J.-Il Jin, N. Tessler. "Ground-State Interaction and Electrical Doping of Fluorinated C60 in Conjugated Polymers", Adv. Funct. Mater., 2009, 21, 4456-4460.

S.M. Advoshenko, I.N. Ioffe, L.N. Sidorov. "Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives", J. Phys. Chem. (A), 2009, 113(40), 10833-10838.

2010

V.A. Ioutsi, A.A. Zadorin, P.A. Khavrel, N.M. Belov, N.S. Ovchinnikova, , A.A. Goryunkov, O.N. Kharybin, E.N. Nikolaev, M.A. Yurovskaya, and L.N. Sidorov. "Diastereoselective lithium salt-assisted 1,3-dipolar cycloaddition of azomethine ylides to the fullerene C60", Tetrahedron, 2010, 66(16), 3037-3041.

Kh. Vorobiev, V. Yu. Markov, N.A. Samokhvalova, P.S. Samokhvalov, S.I. Troyanov, and L.N. Sidorov. "Stable trifluoromethylated fullerene radicals C60(CF3)15 and C60(CF3)17", Mendeleev Comm., 2010, 20(1), 7-9.

N.I. Gruzinskaya, A.I. Silin, A.S. Pimenova, P.A. Khavrel, V.Yu. Markov, L.N. Sidorov, E. Kemnitz, and S.I. Troyanov. "Synthesis and structure of cycloperfluoroalkylated derivatives of C70, C70(C2F4) and C70(C4F8)n, n = 1-6", New J. Chem., 2010, 34, 1-7.

R. Kalinowskia, M. Webera,S.I. Troyanov, C. Paulmann, P. Lugera. "A First Experimental Electron Density Study on a C70 Fullerene: C70(C2F5)10", Z. Naturforsch, 2010, 65b, 1-7.

I.N. Ioffe, C. Chen, S. Yang, L.N. Sidorov, E. Kemnitz, S.I. Troyanov. "Chlorination of C86 to C84Cl32 with Nonclassical Heptagon-Containing Fullerene Cage Formed by Cage Shrinkage", Angew. Chem. Int. Ed., 2010, 49, 4784-4787.

A.I. Druzhinina, R.M. Varushchenko, S.I. Troyanov, L.N. Sidorov. "The standard thermodynamic functions of fullerene chloride", C60Cl30, J. Chem. Thermodynamic, 2010, 42, 165-168.


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